©NACE International. Especially directly above the basin exists a chloride saturated atmosphere, that can freely interact with the materials and when there is no frequent contact with water from the pool, the impact is huge. Ferritic steels are also resistant to cracking but may corrode. There are several types of stress corrosion cracking (SCC), for example, chloride-induced SCC and H2S-induced SCC. Takeaway: Chloride stress corrosion cracking (Cl-SCC) is the most common type of environmentally-induced cracking of austenitic stainless steel. However, the application of highly alloyed ferritic stainless steels is limited due to low toughness and intergranular corrosion attack. Crevice corrosion has proved to be a safety concern of 304L stainless steel spent fuel canisters, when exposed to the saline environments of coastal sites. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking (CSCC). SCC is classified as a catastrophic form of corrosion, as the detection of such fine cracks can be very difficult and the damage not easily predicted. Although no stainless steel grade is totally immune to chloride SCC, the relative resistance of stainless steels varies substantially. The problem itself can be quite complex. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. 1. The straight-chromium ferritic stainless steels, two-phase ferritic-austenitic stainless The required tensile stresses may be in the form of directly applied stresses or in the form of residual stresses. Abstract. SCC requires the simultaneous presence of a corrosive medium, tensile stress (applied or … Chloride Stress Corrosion Cracking (Cl-SCC) is a type of Stress Corrosion Cracking (SCC) and is one of the most well known forms of SCC in the refining and chemical processing industries. This mode of attack is termed stress corrosion cracking (SCC). Stress corrosion cracking occurs in systems made from carbon steel, stainless steel, and other metals, and it requires expert inspection and analysis to find and analyze it. The most common environmental exposure condition responsible for SCC of stainless steels is the presence of chlorides. SCC is the result of a combination of three factors – a susceptible material, exposure to a corrosive environment, and tensile stresses above a threshold. Introduction . Effects of hydrogen charging on the stress corrosion cracking (SCC) behavior of 304 and 310 stainless steels under sustained load were investigated in boiling 42% MgCl 2 solution. Sandvik SAF 2707 HD 3. Sandvik 254 SMO*Material datasheets for Sandvik grades G2MT Labs uses state-of-the-art technology for stress corrosion cracking (SCC) inspection; new technologies that allow early detection and repair/monitoring of areas that are susceptible to SCC. #3 Stress Corrosion Cracking. In comparison, the stress strain curves for 0.15% carbon steel show a loss of about 25% tensile elongation for the same comparison. It has been the observed cause of metal failure in numerous scenarios. Paper presented at Corrosion 2007, Paper 07094, Nashville, Tennessee, 11-15 March 2007. The austenitic grades are also effectively immune to stress corrosion cracking in water at temperature below about 50 °C. Earlier, we introduced a ferritic type stainless steel that is resistant to stress corrosion cracking. This can be seen in the PREN (pitting resistance equivalent number) of duplex stainless steel as well as in its tensile strength. It is concluded that stress corrosion cracking was the main reason for the cracking of the elbow. Testing can be carried out, for example, in boiling 40% CaCl2 or chloride-containing water. Chloride Stress Corrosion Cracking of Austenitic Stainless Steel. stainless steels Corrosion in concrete (corrosion problems are not limited to outside surfaces !) Duplex stainless steels, austenitic stainless steels with a high nickel content (> 25%). Cold deformation and forming, welding, heat treatment, machining and grinding can introduce residual stresses. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. The required tensile stresses may be in the form of directly applied stresses or in the form of residual stresses, see an example of SCC of an aircraft component . The metallurgical influences on the stress corrosion resistance of many commercial stainless steels have been studied using the fracture mechanics approach. For example, copper and its alloys are susceptible to ammonia compounds, mild steels are susceptible to alkalis and stainless steels are susceptible to chlorides. Microbiologically Influenced Corrosion (MIC). Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenance-free service life of the structure. If any one of these factors are eliminated, SCC initiation becomes impossible. In some cases also the duplex grades Sandvik SAF 2205, Sandvik SAF 2507, Sandvik SAF 2707 HD and Sandvik SAF 3207, A corrosive medium - especially chloride-bearing or hydrogen-sulphide (H, The use of material susceptible to stress corrosion cracking (SCC), Stress corrosion cracking (SCC) is characterized by cracks propagating either transgranularly or intergranularly, SCC results from the combined action of three factors; tensile stresses, a corrosive medium and susceptible material, There are several types of stress corrosion cracking (SCC), for example, chloride-induced SCC and H. At a highly increased rate, it is unlike that of other varieties. The following Sandvik grades have very good or excellent resistance to H2S-induced stress corrosion cracking (SCC): Austenitic steels of type ASTM 304 and 316 austenitic steels have limited resistance to stress corrosion cracking (SCC), even at very low chloride contents and temperatures. Also the temperature, the oxygen and chloride contents and the presence of any solid particles, such as sand has to be considered. Sandvik SAF 2507 4. Corrosion resistance of 26%Cr-2%Mo ferritic … The micrograph below (X300) illustrates SCC in a 316 stainless steel chemical processing piping system. This website uses cookies to ensure you get the best experience on our website. As with stress corrosion cracking, residual stresses from manufacturing processes can adversely affect resistance to corrosion fatigue. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and … Screws that are resistant to stress corrosion cracking. Stress corrosion cracking is the failure of austenitic stainless steels caused by the combined action of a corrosive atmosphere and residual stress in the metal. For less demanding environments, duplex steels can be used. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Macroscopically, SCC fractures have a brittle appearance. The problem itself can be quite complex. Stress Corrosion Cracking (SCC) on stainless steel. The risk of stress corrosion cracking (SCC) can be minimized through plant and equipment design. The situation with buried pipelines is a good example of such complexity. Sandvik SAF 3207 2. All rights reserved. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to CSCC. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and use of low carbon steels. Process fluids in wet and sour service within the oil and gas industry often contain a certain amount of hydrogen sulphide, H2S. Chloride-induced SCC is tested experimentally in the laboratory using a chloride-containing environment. This paper presents the results of an examination of cracking discovered in stainless steel anchors in a refractory block destined for inclusion in an ignition hood. Rare, yet severe, stress corrosion cracking is the result of tensile stress combined with elevated temperature, and moisture. A Sandvik grade with very good resistance to this form of stress corrosion cracking is Sanicro 28. Duplex stainless steels, austenitic stainless steels with a high nickel content (> 25%). A disastrous failure may occur unexpectedly, with minimal overall material loss.The micrograph above (X500) illustrates intergranular SCC of an Inconel heat exchanger tube with the crack following the grain boundaries. This has proved to be the greatest hazard with the face-centred cubicstructured austenitic grades, a review concerning which has already appeared in … Experimental SCC data is notorious for a wide range of scatter. These types of stainless steel turned out to be sensitive to chloride induced stress corrosion cracking. When considering the corrosivity of a sour process fluid, the partial pressure of H2S has to be taken into account as well as the pH value. The magnitude and importance of such stresses is often underestimated. Currently, potash plants in Saskatchewan, Canada, are facing several corrosion problems associated with the presence of chloride ions in the potash . The standard 304/304L and 316/316L grades are most susceptible. The corrosion also tends to occur in an environment where stress is applied to the components. It typically occurs in alloys, such as stainless steel, and not in pure metals. It’s when austenitic stainless steel and ferritic stainless steel are put together that they become truly resistant to stress corrosion cracking. Stress corrosion cracking is cracking due to a process involving conjoint corrosion and straining of a metal due to residual or applied stresses.1 Despite the introduction of polymers and composites in recent years, metals remain important in structures because of their strength, stiffness, toughness and tolerance of high temperatures. Sanicro 28 6. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cure-all for corrosion problems. The production mat of ferritic stainless steels is lower than austenitic stainless steels. The combination of tensile stress and a specific corrosive environment can crack stainless steels. In the microstructure, these cracks can have an intergranular or a transgranular morphology. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Supermartensitic stainless steels (SMSS), including both lean grades (without molybdenum) and high … Stress corrosion cracking (SCC) is the cracking induced from the combined influence of tensile stress and a corrosive environment. The impact of SCC on a material usually falls between dry cracking and the fatigue threshold of that material. It has been shown that H2S-induced stress corrosion cracking attack is worst at temperatures around 80°C (176°F), but cracking can occur also at temperatures below 60°C (140°F). Corrosion fatigue can occur at ambient temperature and in environments that could be considered harmless with regard to other forms of corrosion. [5, 12, 13]. An extensive study was conducted on the susceptibility of Type 347 stainless steel to stress-corrosion cracking in high temperature water over wide ranges of chloride concentration, temperature, oxygen concentration, and pH. Other problems that have been observed with Inconel include wastage, tube denting, pitting, and intergranular attack. In many cases, problems with stress corrosion cracking (SCC) can be solved by selecting a suitable material. Stress corrosion cracking (SCC) is the cracking induced from the combined influence of tensile stress and a corrosive environment. Despite the extensive qualification of Inconel for specific applications, a number of corrosion problems have arisen with Inconel tubing. Stress corrosion cracking (SCC) results from the combined action of three factors: A precursor of stress corrosion cracking in chloride-bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. This type of decomposition can break down the mechanical properties of steel in days rather than months or years. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Stress Corrision Cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. SCC can occur typically in hot water tanks or swimming pools. The stress-corrosion cracking of screws is a phenomenon where corrosion-resistant materials, such as stainless steel, become cracked and damaged. 1 In 1985, 12 people were killed in Uster, Switzerland when the concrete roof of a swimming pool collapsed. Chloride stress corrosion cracking (CSCC) is a type of intergranular corrosion. Abstract. similar stress strain curve for duplex stainless steel. For less demanding environments, duplex steels can be used. Laboratory testing can be carried out according to NACE TM0177 (5% NaCl and 0.5% acetic acid saturated with H2S) or in relevant simulated service environments at elevated temperature and pressure. . The impact of SCC on a material usually falls between dry cracking and the fatigue threshold of that material. The cracking was accelerated by the incorporation of hydrogen into the steel without altering the crack growth mechanism. * 254 SMO is a trademark owned by Outokumpu OY, Sandvik is an engineering group in materials technology, metal-cutting, and mining and rock excavation.Visit Sandvik Group's website, Copyright © Sandvik AB; (publ)SE-811 81 Sandviken, SwedenPhone: +46 26 26 00 00. We offered a "duplex stainless steel screw" that mixes austenite and ferrite stainless, thereby bestowing on it the advantages of high strength and corrosion … As with stress corrosion cracking is Sanicro 28 for the cracking induced from the corrosion and! Nature of the elbow Switzerland when the concrete, providing a long, maintenance-free service life of the.... Oxygen, chloride ions and high temperature or in the form of directly applied stresses or in the.! On the stress corrosion cracking ( Cl-SCC ) is the presence of chloride in. 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